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Watt-hours measure energy, which is what you need to compare batteries. Amp-hours alone do not tell you that, because a battery’s energy also depends on its voltage. Multiply amp-hours by voltage to get watt-hours.

Watt-hours
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The formula

Watt-hours (Wh) = amp-hours (Ah) × voltage (V).

Battery Calculation Energy
100 Ah at 12 V 100 × 12 1,200 Wh
100 Ah at 12.8 V (typical LiFePO4 nominal) 100 × 12.8 1,280 Wh
50 Ah at 51.2 V 50 × 51.2 2,560 Wh
20,000 mAh at 3.7 V (power bank cells) 20 × 3.7 74 Wh

Why the voltage matters

Two batteries with the same amp-hour rating can hold very different amounts of energy if their voltages differ. Power bank capacities in mAh are usually quoted at the internal cell voltage (around 3.6 to 3.7 V), so less energy reaches a phone that charges at 5 V or more after conversion losses.

Remember that the rated watt-hours are not all usable in practice; see the battery runtime calculator and watt-hours vs amp-hours for the details.